A man works in an aluminum smelter for 12years. the drinking water in the smelter contains0.075mg/l arsenic and 0.580mg/l methylene chloride. his only exposure to these chemicals in water is at work.
a. What is the hazard index (HI) associated with this exposure?
b. Does the HI indicate this is a safe level of exposure?
C. What is the incremental lifetime cancer risk for the man due solely to the water he drinks at work? Does it seem to be an acceptable risk according to EPA?

Answers

Answer 1

a. The hazard index is the sum of the individual hazard quotients for each chemical.

b. The HI indicates a potential health risk.

c. The incremental lifetime cancer risk is a measure of the additional risk of developing cancer over a lifetime due to exposure to a chemical.

a. Assuming the man weighs 70 kg and drinks 2 L of water per day, the HQs are 0.015 for arsenic and 0.405 for methylene chloride, giving an HI of 0.42.

b. The HI indicates a potential health risk, as an HI greater than 1 indicates a potential for adverse health effects.

c. The ILCR for methylene chloride is \(5.6 * 10^{-5}\), which is also above the acceptable risk level, indicating a potentially increased risk of cancer from methylene chloride exposure.

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Related Questions

I WILL GIVE BRAINLIEST PLEASE ANSWER

I WILL GIVE BRAINLIEST PLEASE ANSWER

Answers

Answer:

b. 1...1...1

Explanation:

If you were going to cook spaghetti in boiling water, which compound would you
put in the water to speed up the cooking by increasing boiling point? *

salt (ionic)

sugar (covalent)

nothing just water

Answers

If you were going to cook spaghetti in boiling water, the compound that should be put in the water to speed up the cooking by increasing boiling point is salt (ionic). 

Salt and boiling point

The boiling point is the temperature at which the liquid turns to vapor. It happens when the vapor pressure equals the pressure of the surrounding air.

The boiling point for water is 100 degrees Celsius at sea level. It needs a bit of energy to make water to a boil. In fact, you need 1 calorie of energy to raise 1 gram of water by 1 degree Celsius. 

The way to raise the boiling point of a liquid is by increasing the temperature or adding a solute, such as salt. Adding a solute to the liquid will create stronger bonds between molecules. It makes the water molecules to escape from the pot harder.

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What is the tertiary consumer in this food chain?
A hawk
B lettuce
C snail
D thrush

What is the tertiary consumer in this food chain?A hawkB lettuceC snailD thrush

Answers

Answer:

the hawk

Explanation:

in order it would be: producer, primary, secondary, tertiary

Answer:

the hawk is the tertiary consumer

How many moles of aluminum are required to produce 495.0 grams of H2? 6NaOH + 2AI -> 2Na3AlO3 + 3H2

Answers

Taking into account the reaction stoichiometry, 165 moles of Al are required to produce 495.0 grams of H₂.

Reaction stoichiometry

In first place, the balanced reaction is:

6 NaOH + 2 Al  → 2 Na₃AlO₃ + 3 H₂

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

NaOH: 6 molesAl: 2 molesNa₃AlO₃: 2 moles H₂: 3 moles

The molar mass of the compounds is:

NaOH: 40 g/moleAl: 27 g/moleNa₃AlO₃: 144 g/moleH₂: 2 g/mole

By reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

NaOH: 6 moles ×40 g/mole= 240 gramsAl: 2 moles ×27 g/mole= 54 gramsNa₃AlO₃: 2 moles ×144 g/mole= 288 gramsH₂: 3 moles ×2 g/mole= 6 grams

Mass of Al required

The following rule of three can be applied: If by reaction stoichiometry 6 grams of H₂ are produced by 2 moles of Al, 495 grams of H₂ are produced by how many moles of Al?

moles al Al= (495 grams of H₂×2 moles of Al) ÷6 grams of H₂

moles of Al= 165 moles

Finally, 165 moles of Al are required.

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True or False: A neutrally charged atom has an equal number of protons and electrons.

Answers

Answer:

True

Explanation:

Answer:

True

Explanation:

A neutral atom must have an equal amount of protons as electrons.  

why is nitrogen the most common gas in earths atmosphere astr 1010

Answers

Nitrogen is the most common gas in Earth's atmosphere primarily because of its stable molecular structure and abundance in Earth's crust. It makes up about 78% of the atmosphere and plays a crucial role in supporting life on Earth.

Nitrogen gas (N2) is abundant in the atmosphere due to several factors. Firstly, nitrogen is a relatively inert gas, meaning it does not readily react with other elements or compounds. This stability allows nitrogen to accumulate in the atmosphere over long periods of time. Additionally, nitrogen is a major component of organic matter and is recycled through various biological and geological processes, contributing to its abundance. Nitrogen-fixing bacteria in the soil and legume plants also convert atmospheric nitrogen into forms usable by other organisms.

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How do the gravitational forces change as the objects get closer to each other?

Answers

Answer:

you can use the example of two magnets

Answer: The gravitational force Increase as the objects get closer.

Explanation:

calculate the mass of glucose that contains a million oxygen atoms. be sure your answer has a unit symbol if necessary, and round it to significant digits.

Answers

The mass of glucose which contains a million oxygen atoms is 0.002 g as 1 glucose molecules contains 6 oxygen atom.

Glucose is defined as a sugar having the molecular formula \(C_{6} H_{12} O_{6}\). It is the most abundant monosaccharide. It is the subcategory of carbohydrates. It is mainly made by plants and most algae during photosynthesis from water and carbon dioxide using energy from the sunlight as it is used to make cellulose in cell walls. Glucose is classified as a monosaccharide containing six carbon atoms and consist of an aldehyde group.

1 glucose molecule contains 6 oxygen atoms.

so, = 2.66 x \(10^{-17}\) g) / ( 6 x 1.66 x 10^-22 g/mole)

    = 0.002 g

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If you have 60 moles of HCl, what should the volume of solution be to make a 10 M solution?

Answers

Answer:10

Explanation:

Multiply the volume by the density to get the mass.

Divide the mass by the molar mass to get the number of moles.

Predict whether or not the substances in the table will sublime at STP. Base your predictions only on the type of force holding the solid together.

Predict whether or not the substances in the table will sublime at STP. Base your predictions only on

Answers

The states of matter of the materials;

1) Dispersion forces - Yes

2) Hydrogen bonding - No

3) Ionic - No

4) Dispersion forces - No

5)  Dispersion forces - Yes

6) Ionic  - No

7) Hydrogen bonding - No

What is the sublimation?

Sublimation is a physical process in which a substance transitions directly from its solid phase to its gaseous phase without passing through the intermediate liquid phase. In sublimation, the solid substance is heated, and the resulting gas molecules escape from the solid lattice structure without the need for melting.

One common example of sublimation is the process of dry ice. Dry ice is solid carbon dioxide (CO2) that sublimes at a temperature of -78.5 degrees Celsius (-109.3 degrees Fahrenheit). When dry ice is exposed to room temperature, it transitions directly from a solid to a gas, producing a fog-like effect.

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295 mL of a 1. 00 M ammonium chloride (NH4CI) solution is diluted with 2. 25 L of water. What is the new concentration in molarity?

Answers

Answer:

Explanation:

To find the new concentration of the solution, we need to use the dilution formula:

C1V1 = C2V2

Where C1 is the initial concentration, V1 is the initial volume, C2 is the final concentration, and V2 is the final volume.

In this case, the initial concentration is 1.00 M and the initial volume is 295 mL, while the final volume is 2.25 L. We can plug these values into the dilution formula to solve for the final concentration:

C2 = (C1V1)/V2

= (1.00 M)(295 mL)/(2.25 L)

= 0.131 M

Therefore, the new concentration of the solution is 0.131 M.

differences between mixtures and elements

Answers

Mixtures are a group of elements that are mixed together but not chemically combined

Elements are the fundamental materials of which all matter is composed.

Element: A substance that is made up of only one type of atom. Compound: A substance that is made up of more than one type of atom bonded together. Mixture: A combination of two or more elements or compounds which have not reacted to bond together

Very simple ques. When a substance dissolves it-- *
1 changes its physical state
2 melts.
3 breaks down into smaller pieces.

Answers

Number 3 breaks down into smaller pieces

what will be the result of the reaction
(CH3COO)2+redP +Cl2

Answers

Answer:

(CH3COO)2 + redP + Cl2 → ClCH2COOH + HCl

Explanation:

This is an example of halogenation of carboxylic acids at alpha carbon atom. In this reaction, red phosphorus and chlorine are treated with carboxylic acids having alpha hydrogen atom followed by hydrolysis to form alpha chloro carboxylic acid.

Aluminum is reacted with calcium chloride and produces calcium and aluminum chloride. If 4.7 grams of calcium chloride are completely used up in the
reaction, how many grams of calcium will be produced?

Answers

Approximately 1.693 grams of calcium will be produced when 4.7 grams of calcium chloride are completely used up in the reaction.

To determine the grams of calcium produced, we need to calculate the molar ratio between calcium chloride (CaCl2) and calcium (Ca) in the balanced chemical equation for the reaction. The balanced equation is:

2Al + 3CaCl2 → 3Ca + 2AlCl3

From the balanced equation, we can see that for every 3 moles of calcium chloride, 3 moles of calcium are produced. We need to convert the given mass of calcium chloride (4.7 grams) to moles using its molar mass.The molar mass of CaCl2 is calculated by adding the atomic masses of calcium (Ca) and chlorine (Cl). The atomic mass of calcium is 40.08 g/mol, and the atomic mass of chlorine is 35.45 g/mol.

Molar mass of CaCl2 = (40.08 g/mol) + 2(35.45 g/mol) = 110.98 g/mol

Now we can calculate the moles of calcium chloride:

Moles of CaCl2 = (mass of CaCl2) / (molar mass of CaCl2)

              = 4.7 g / 110.98 g/mol

              ≈ 0.0423 mol

Since the molar ratio between calcium chloride and calcium is 3:3, the moles of calcium produced will be equal to the moles of calcium chloride used.

Moles of Ca = 0.0423 mol

To convert moles of calcium to grams, we multiply by the molar mass of calcium:

Mass of Ca = (moles of Ca) × (molar mass of Ca)

          = 0.0423 mol × 40.08 g/mol

          ≈ 1.693 g

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using hess's law, calculate δh° for the process: sb (s) cl2 (g) sbcl5 (s) from the following information: sb (s) cl2 (g) sbcl3 (s) δh° = − 314 kj sbcl3 (s) cl2 (g) sbcl5 (s) δh°= − 80 kj

Answers

The δh° for the process SB (s) + Cl2 (g) → SbCl5 (s) is -394 kJ using Hess's-Law.

What is the value of ΔH° for the process SB (s) + Cl2 (g) → SbCl5 (s) using Hess's Law?

Hess's Law states that the enthalpy change of a reaction is independent of the pathway taken and depends only on the initial and final states. By combining the given reactions, we can cancel out the intermediate compound (SbCl3) and obtain the desired reaction. The enthalpy change for the first reaction (SB (s) + Cl2 (g) → SbCl3 (s)) is -314 kJ, and for the second reaction (SbCl3 (s) + Cl2 (g) → SbCl5 (s)) is -80 kJ. By adding these two reactions, we obtain the overall reaction with a δh° of -394 kJ.

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Which state of matter usually has the lowest density? Question 1 options: a cool solid a warm solid a cool liquid a warm liquid.

Answers

A warm liquid usually has the lowest density among the given options.

Generally, substances expand and become less dense as they are heated, and this behavior is commonly observed in liquids. As a liquid is warmed, the molecules gain kinetic energy and move more rapidly, leading to an increase in the average distance between the particles. This expansion results in a decrease in the density of the liquid.

On the other hand, solids tend to have a higher density compared to liquids. While cooling a solid may cause a decrease in its volume, the change is usually not significant enough to make it less dense than a warm liquid.

Therefore, among the given options, a warm liquid is likely to have the lowest density.

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Which of the fallowing scientific claims about the bond in the molecular compound HF is most likely to be true?
There is a partial negative charge on the H atom.
Electrons are shared equally between the H and F atom.
The bond is extremely weak.
The bond is highly polar.

Answers

The bond is highly polar is the scientific claim about the bond in the molecular compound HF is most likely to be true.

The term polar means that there is separation of charges, the bonds will be the more polar the greater the difference in electronegativity between the bonded atoms.

In hydrogen fluoride, for example, F is more electronegative than H because its nucleus, with 9 positive charges, attracts e-shares with H more strongly than the nucleus of H, with only one positive charge.

Therefore, the e- shared by covalence will be closer to F than to H and the molecule forms a permanent dipole.

Therefore, we can conclude that the bond is highly polar is the scientific claim about the bond in the molecular compound HF is most likely to be true.

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Hydrogen gas reacts with chlorine gas to form hydrogen chloride as shown in the following reaction: H2 (9) + Cl2 (g) + 2HCl (9) If a 454.4 g sample of chlorine gas (MM = 71.0 g/mol) was reacted with excess hydrogen at 565 K and 2.30 atm, how many grams of hydrogen chloride gas (MM = 36.5 g/mol) are produced? g Your answer should be rounded to three significant figures. Do not include units in your answer​

Answers

Answer:

467

Explanation:

ncl2 = 454.4x1/(71.0 g/mol) = 6.40 mols cl2

6.40 mols cl2 x 2molsHCL/1moleCL2 x 36.5g/1moleHCL = 467 g HCL

One mole of chlorine gas gives two moles of hydrogen chloride. Thus, 454.4 g of chlorine gas will give 467.2 g of hydrogen chloride.

What is hydrogen chloride?

Hydrogen chloride is a covalent compound formed by the electron sharing of chlorine and hydrogen. It normally exists in gaseous state and can be liquified to the acidic form.

As per the balanced reaction one mole of chlorine gas gives two moles of hydrogen chloride gas. The molecular mass of chlorine gas is 71 g/mol. The molar mass of HCl is 36.5 g/mol.

Hence, 71 g of chlorine gas gives 73 g of HCl. Then, the mass of HCl produced from 454.4 g of chlorine gas is calculated as follows:

mass of HCl = (454.4 × 73) / 71

                     = 467.2 g.

Therefore, the mass of HCl produced from 454.4 g of chlorine gas is 467.2 g.

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which would most likely cause a rise in sea levels

which would most likely cause a rise in sea levels

Answers

Answer:

B. melting of ice caps

Explanation:

the melting of polar ice caps

Which of the following is a standardized and convenient unit to use for comparing distances across the Solar System?
A
the distance from the Sun to Earth
B. the distance light travels in one year
C the distance Mercury travels in one year
D. the distance Earth travels around the Sun

Answers

C - the distance Mercury travels in one year
C. i’m pretty sure
hope this helped


Scientists have measured a cheetah running across the savannah at 70 m/s. Which of the foolowing pieces of
data accurately measured the cheetah's speed?

Answers

Answer:

You haven't provided us with ' the following pieces of

data'

A 100mL sample of 0.1MMgCl2(aq) and a 100mL sample of 0.2MNaOH(aq) were combined, and Mg(OH)2(s) precipitated, as shown by the equation above. If the experiment is repeated using solutions of the same molarity, which of the following changes in volume will double the amount of Mg(OH)2(s) produced?

a. Using the same volume of MgCl2(aq) but twice the volume of NaOH(aq)
b. Using twice the volume of MgCl2(aq) but half the volume of NaOH(aq)
c. Using twice the volume of MgCl2(aq) but the same volume of NaOH(aq)
d. Using twice the volume of MgCl2(aq) and twice the volume of NaOH(aq)

Answers

Answer:

Using twice the volume of MgCl2(aq)MgCl2(aq) and twice the volume of NaOH(aq)NaOH(aq)

Explanation:

The amount of Mg(OH)2 is doubled when the volume of the reactants is doubled because they still react in the ratio of 2:1.

The reaction between MgCl2 and NaOH occurs as follows;

MgCl2(aq) + 2NaOH(aq) -----> Mg(OH)2(s) + 2NaCl(aq)

We can see that the mole ratio of the reactants is 1:2.

Initial number of moles of MgCl2 = 100/1000 L × 0.1 M = 0.01 moles

Initial number of moles of NaOH =  100/1000 L × 0.2 M = 0.02 moles

If i double the volume of each reactant;

Number of moles of MgCl2 = 200/1000 L  × 0.1 M = 0.02 moles

Number of moles of NaOH =  200/1000 L  × 0.2 M = 0.04 M

We can see that the amount of Mg(OH)2 is doubled when the volume of the reactants is doubled because they still react in the ratio of 2:1.

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When writing the chemical formulas for a molecular compound, what method do you use?​

Answers

Answer:

A molecular compound is usually composed of two or more nonmetal elements. Molecular compounds are named with the first element first and then the second element by using the stem of the element name plus the suffix -ide.

A valid Lewis structure of _____ cannot be drawn without the central atom violating the octet rule.
a. NI3
b. SO3
c. SF4
d. SrF4
e. CO2

Answers

A valid Lewis structure of SO3 cannot be drawn without the central atom violating the octet rule. The correct option is b.

The octet rule states that atoms tend to gain, lose, or share electrons in order to achieve a stable electron configuration with eight electrons in their outermost shell.

In the case of SO3, sulfur (S) is the central atom surrounded by three oxygen (O) atoms. Each oxygen atom needs two electrons to complete its octet, while sulfur needs six electrons to complete its octet.

However, if we distribute the electrons according to the octet rule, each oxygen atom would share two electrons with sulfur, leaving sulfur with only six electrons.

One possible Lewis structure for SO3 is to form a double bond between sulfur and one oxygen atom and single bonds with the remaining two oxygen atoms. In this structure, sulfur has ten electrons around it, violating the octet rule.

The Lewis structure would look like this:

O

//

S

\

O

To accommodate the octet rule, sulfur in SO3 can expand its valence shell by utilizing its empty d orbitals. This allows sulfur to accommodate more than eight electrons around it, but it violates the octet rule.

In summary, a valid Lewis structure of SO3 cannot be drawn without the sulfur atom violating the octet rule because sulfur would require more than eight electrons to satisfy the octet rule. The correct option is b.

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According to the diagram which statement best describes what happens when two astronauts collide in space? Will give crown!!!!

According to the diagram which statement best describes what happens when two astronauts collide in space?

Answers

Answer:

J. Their momentum is conserved

Explanation:

According to the diagram, the best statement that describes what happens when two astronauts collides in space is that their momentum is conserved.

The momentum before collision is 320kgkm/hr and after collision it is 320kgm/s

 This collision is an inelastic collision;

    momentum before  = momentum after

              m₁v₁ + m₂v₂     =       v(m₁ + m₂)

m₁ = 80kg

v₁  = 4km/hr

m₂ = 80kg

v₂  = 0

v  = 2km/hr

 Insert the parameters;

              (80 x 4) + (80 x 0)    = 2(80 + 80)

                    320                      = 320

what is the uncertainty in the molarity of your edta titrant? show your worked out solution in the space provided below and enter your final answer for standard deviation and percent relative standard deviation.

Answers

The standard deviation and per cent relative standard deviation, which represent the uncertainty in the molarity of your EDTA titrant.

To calculate the uncertainty in the molarity of your EDTA titrant, we need some information about the measurements taken during the titration process. However, since the information is not provided, I will give you a general step-by-step guide to finding the uncertainty in molarity:
1. Record the volume measurements (in mL) for each titration trial.
2. Calculate the molarity of the EDTA titrant for each trial using the balanced equation of the reaction and the known molarity and volume of the analyte solution.
3. Find the mean (average) molarity of the EDTA titrant by summing the molarities calculated in step 2 and dividing by the total number of trials.
4. Calculate the deviation for each trial by subtracting the mean molarity from the molarity of each trial.
5. Square each deviation calculated in step 4.
6. Sum the squared deviations and divide by the total number of trials minus one (n-1) to find the variance.
7. Calculate the standard deviation by taking the square root of the variance.
8. Calculate the per cent relative standard deviation by dividing the standard deviation by the mean molarity and multiplying by 100.
After following these steps, you will have found the standard deviation and per cent relative standard deviation, which represents the uncertainty in the molarity of your EDTA titrant.

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If nitrogen and hydrogen combine in a combustion reaction, what would the product of the reaction be?

CH4 + 2O2 → ____2 + 2H2O

Answers

Co2

Explanation:

CH4 (g) + 2 O2 (g) → CO2 (g) + 2 H2O (l)

Answer:

C - CO

Explanation:

Correct on EDGE

reflection obtained from a smooth surface is called a

a- regular reflection
b- irregular reflection
C- both a & b
D- none

Answers

The answer is A.regular reflection

Hope this helps.

Suggest a way that a scientist could create an even more accurate model of universe expansion

Answers

Answer:

Between galaxies, retake the measurement.

Explanation:

Among both galaxies, reiterate the measurements. Instead of utilising a balloon, a scientist might create a model that shows in which everything really is and how cosmos is expanding rather than expanding. By inflating up the atmosphere to 1/2, 3/4, and full size, continue the operation.

Other Questions
r(t) does not use arc length as a parameter a description of the curve that uses arc lenqth as a parameter is solo services, inc. was a select answer . a business of this type select answer considered a separate legal entity from its owners. when toby solo set up an account for solo services, inc. with lakes express, select answer would be liable for any charges on that account. assessment question toby solo select answer a shareholder in solo services, inc. one of the advantages of being a shareholder in a corporation is the select answer liability of shareholders. the principle of limited shareholder liability means that shareholders are not personally liable for the debts of the corporation beyond select answer . if solo services, inc., was dissolved, and assets were distributed, then toby solo likely select answer the value of his investment. toby solo select answer have had assets outside of the company that he would have been allowed to keep when the company was dissolved. assessment question if lakes express is attempting to receive payment from the extra assets of a shareholder, it would be asking the court to select answer . courts will ignore the corporate structure and make the shareholder-owners personally liable when the corporate structure is select answer for personal benefit or when the corporate form is select answer from the controlling shareholder. assessment question in this situation, it select answer that lakes express was tricked into dealing with the corporation instead of the individual. given the life of the corporation, it select answer that the corporation was set up to always be insolvent, or was undercapitalized. it also select answer that the corporation was formed to evade a legal obligation. there select answer evidence that the corporate formalities were not followed and there select answer evidence that toby solo commingled funds. given these facts, a court select answer pierce the veil of solo services, inc., and hold toby solo personally responsible for the debt. assessment question what if the facts were different? assume that in addition to the facts given, that evidence was presented to the court that solo, his wife, and their kids regularly used the account at lakes express to fill up their personal vehicles. does this change the outcome? given this new evidence, a court likely select answer find that lakes express was tricked or misled into dealing with the corporation rather than the individual. the court likely select answer find that the corporation was undercapitalized, created to evade an existing legal obligation, or failed to comply with the required corporate formalities and meetings. the court likely select answer find that the personal and corporate interests were commingled to such an extent that the corporation had no separate identity with regard to the relationship with lakes express. because of these findings, the court likely select answer pierce the corporate veil and hold toby solo personally responsible for the debt to lakes express. Solve the system of linear equations using the Gauss-Jordan elimination method. 2x + 2y 3z 10 2x 2y + 3z -2 y + 3z = 2 4x (x, y, z) = A company broke even last year with sales of $100,000. Each item had variable cost of $3.00 and a sales price of $5.00. How much do they need to sell this year to earn net income of $14,000 after-tax. Tax rate = 30%. Assume no change in cost behavior. % Last Year This Year Sales $100,000 -Variable Costs =Contribution Margin -Fixed Costs =Operating income (loss) -Tax (30%) =Net income $14,000 after a few months working as a professional organizing consultant, kurumi was passionate about her job because every day brought a client with a closet, an office, or a garage that was a bigger challenge. Help please on this math problem asap35 POINTS Name the type of food additive that stops the food reacting with oxygen. Explain why Sa f(x)dx = 0 (Hint: Use the First Fundamental Theorem of Calculus) 4. 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S, Manuela 1 of 1 compra.Question 6 with 1 blankNecesita lpices especiales el estudiante? No, el estudiante no 1 of 1 necesita.Question 7 with 1 blankCierran las puertas cuando empieza el examen? S, 1 of 1 cierran cuando empieza el examen.Question 8 with 1 blankVes mi computadora nueva? S, 1 of 1 veo.Question 9 with 1 blankEscuchan el programa de radio David y Sonia? S, David y Sonia 1 of 1 escuchan.Question 10 with 1 blankOyen ustedes a los nios en el patio? No, no 1 of 1 omos. What does hemingways indirect characterization of the narrator reveal? the narrator agrees with passini, although he does not admit this. the narrator recognizes that war is cruel, unjust, and inescapable. the narrator has little patience for opposing reasoning. the narrator tends to patronize those who disagree with him. If the pH of pure water is 7, ammonia is 12, and coffee is 5, which is acidic, which isneutral, and which is basic? Write the coordinates of the vertices after a translation 4 units left. Does sushi have regional variations? Calculate Delta H r* n for Ca(s) + 1/2 * O_{2}(g) + C*O_{2}(g) -> CaC*O_{3}(s)